Aryl-bis-(scorpiand)-aza receptors differentiate between nucleotide monophosphates by a combination of aromatic, hydrogen bond and electrostatic interactions
نویسندگان
چکیده
منابع مشابه
A thermodynamic insight into the recognition of hydrophilic and hydrophobic amino acids in pure water by aza-scorpiand type receptors.
Interactions of different hydrophilic (His, Asp, Glu,) and hydrophobic (Ala, Phe, Tyr, Trp) amino acids in water with a scorpiand aza-macrocycle (L1) containing a pyridine group in the ring and its derivative (L2) bearing a naphthalene group in the tail have been analysed by potentiometric and calorimetric measurements. Theoretical calculations corroborate that major attractive forces that hold...
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Quantitative studies of the 1 : 1 complexes formed between perfluorohexyl iodide and a variety of hydrogen-bond acceptors have been used to probe the relationship between halogen bonding, hydrogen bonding, desolvation and the electrostatics of non-covalent interactions.
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We have designed and synthesized a new ligand, 6-(2-pyridinyl)-4-[3'-(3-pyridinyl)[1,1'-biphenyl]-3-yl]-2,2'-bipyridine (2). 2 reacted with Pt(cod)(MeCN)(2)(BF(4))(2) to quantitatively give the molecular dimer, 1.BF(4) (2(2).Pt(II)(2).4BF(4)(-)), by self-assembly. The (1)H NMR and UV-vis titration showed that the complexation affinity of 1.BF(4) toward benzenediol guests decreases in the order ...
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Simple energy calculations show that there is a significant interaction between a hydrogen bond donor (like the greater than NH group) and the centre of a benzene ring, which acts as a hydrogen bond acceptor. This interaction, which is about half as strong as a normal hydrogen bond, contributes approximately 3 kcal/mol (1 cal = 4.184 J) of stabilizing enthalpy and is expected to play a signific...
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ژورنال
عنوان ژورنال: Organic & Biomolecular Chemistry
سال: 2015
ISSN: 1477-0520,1477-0539
DOI: 10.1039/c4ob02084g